SYNTHESIS AND REACTIVITY OF (C5H4PPH2, BH3)2U(BH4)2 AN UNUSUAL ELECTRON-POOR CYCLOPENTADIENYL COMPLEX

Authors
HAFID A DORMOND A BAUDRY D
Citation
A. Hafid et al., SYNTHESIS AND REACTIVITY OF (C5H4PPH2, BH3)2U(BH4)2 AN UNUSUAL ELECTRON-POOR CYCLOPENTADIENYL COMPLEX, New journal of chemistry, 18(5), 1994, pp. 557-559
Citations number
12
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
18
Issue
5
Year of publication
1994
Pages
557 - 559
Database
ISI
SICI code
1144-0546(1994)18:5<557:SARO(B>2.0.ZU;2-0
Abstract
Borane complexation on the phosphorus atom of diphenylphosphidocyclope ntadienyl-uranium complexes modelized f-d heterobimetallics with the d metal bonded to the phosphorus. Like the d metal moiety, the coordina ted borane induces a strong electron withdrawing effect.