Five tannin fractions were isolated from grape (Vitis vinifera) seeds.
HPLC analysis of the degradation products released by thioacidolysis
showed that all fractions consisted of catechin, epicatechin and epica
techin gallate units. Epicatechin was the major component in the exten
ded chain. Catechin was more abundant in terminal units than in extens
ion units. The proportion of galloyllated units varied from 13% to 29%
as the M(r) increased. Mean degrees of polymerization ranging from 2.
3 to 15.1 (by thiolysis) and from 2.4 to 16.7 (by GPC) were determined
.