A CHEMICO-ENZYMATIC SYNTHESIS OF ALL 4 STEREOISOMERS OF 1,6-DIMETHYLOCT-1-YL FORMATE, AN AGGREGATION PHEROMONE MIMIC FOR THE SMALLER FLOUR BEETLE

Citation
Gd. Gamalevich et Ep. Serebryakov, A CHEMICO-ENZYMATIC SYNTHESIS OF ALL 4 STEREOISOMERS OF 1,6-DIMETHYLOCT-1-YL FORMATE, AN AGGREGATION PHEROMONE MIMIC FOR THE SMALLER FLOUR BEETLE, Mendeleev communications, (2), 1994, pp. 40-41
Citations number
9
Categorie Soggetti
Chemistry
Journal title
ISSN journal
09599436
Issue
2
Year of publication
1994
Pages
40 - 41
Database
ISI
SICI code
0959-9436(1994):2<40:ACSOA4>2.0.ZU;2-I
Abstract
(2R,6R)-, (2R,6S)-, (2S,6R)- and (2S,6S)-2,6-dimethyloct-1-yl formates have been prepared from S-(+)- and R-(-)-enantiomers of 3,7-dimethylo cta-1,6-diene via enantioselective hydrolysis of (2R/S,6R)- and (2R/S, 6S)-2,6-dimethyloct-1-yl formates with porcine pancreatic lipase as th e key step.