Yn. Bubnov et al., SYNTHESIS OF NOVEL METHYL-SUBSTITUTED 1-AZAADAMANTANES FROM 1-BORAADAMANTANE DERIVATIVES, Mendeleev communications, (2), 1994, pp. 43-45
Three new homologues of 1-azaadamantane (2-Me, 2,2- and 3,5-Me2) have
been prepared from the corresponding 1-boraadamantane compounds; the k
ey stage in the transformation is an intramolecular 1,2-anionotroPic r
earrangement of the omega-azidoalkylborane intermediate.