RADIATION STABILITY OF 15-CROWN-5 COMPLEXES WITH ALKALINE-EARTH METALCHLORIDES

Citation
Ei. Grigorev et al., RADIATION STABILITY OF 15-CROWN-5 COMPLEXES WITH ALKALINE-EARTH METALCHLORIDES, Mendeleev communications, (2), 1994, pp. 66-67
Citations number
8
Categorie Soggetti
Chemistry
Journal title
ISSN journal
09599436
Issue
2
Year of publication
1994
Pages
66 - 67
Database
ISI
SICI code
0959-9436(1994):2<66:RSO1CW>2.0.ZU;2-2
Abstract
The radiation stability of complexes with 15-crown-5 and alkaline eart h metal chlorides has been investigated by EPR spectroscopy and gas ch romatography; the resistance of the complexes to rupture of the ring i s determined by the energy of the interaction between the cation and t he polyether and energy transfer from the metal to the organic ligand was noted.