CONDUCTIVITY OF POLYANILINE AND ITS DERIVATIVES INCORPORATED WITHIN THE CAVITIES OF THE 3-DIMENSIONAL [TRIS(TRIMETHYLTIN)HEXACYANO-FERRATE]

Authors
ETAIW SEH IBRAHIM AMA
Citation
Seh. Etaiw et Ama. Ibrahim, CONDUCTIVITY OF POLYANILINE AND ITS DERIVATIVES INCORPORATED WITHIN THE CAVITIES OF THE 3-DIMENSIONAL [TRIS(TRIMETHYLTIN)HEXACYANO-FERRATE], Thermochimica acta, 233(2), 1994, pp. 297-307
Citations number
35
Categorie Soggetti
Chemistry Analytical
Journal title
Thermochimica acta → ACNP
ISSN journal
00406031
Volume
233
Issue
2
Year of publication
1994
Pages
297 - 307
Database
ISI
SICI code
0040-6031(1994)233:2<297:COPAID>2.0.ZU;2-B
Abstract
The dependence of the electrical conductivity of aniline and its deriv atives in situ intercalated within the cavities of the three dimension al polymeric host [(Me3Sn)3Fe(CN)6]infinity, on temperature has been i nvestigated. The conductivity values at 303 K, the activation energies and the energy gaps have been calculated. These novel polymeric inter calated complexes behave as good semiconductors. The conductivity depe nds on the structure of the aniline derivative and the conditions of t he reaction.