A spectrometer using a monomode tunable diode laser as a source is des
cribed. The phase of the emission is controlled by the interference pa
ttern given by a Michelson interferometer. The phase noise is thus dra
stically reduced and the wavenumber measurement precision is better th
an 10(-8). Also, the intensity absorbed by a gas is known to a precisi
on better than 10(-3). To illustrate the possibilities of the spectrom
eter, brief examples of inelastic molecular collision effects in gases
(pressure broadening, mixing, and shift for V-R lines) will be given.
The low noise level and precise wavenumber measurements allowed Pliva
to build an effective absorption spectrum with linewidths significant
ly narrower than Doppler-limited ones using deconvolution methods. (C)
1994 Academic Press, Inc.