F. Rachet et al., LINESTRENGTH MEASUREMENTS FOR THE 30(0)0[-02(0)0, 10(0)1[-01(1)0, AND13(1)0[-00(0)0 TRANSITIONS OF (N2O)-N-14-O-16 (2600-3100 CM-1), Journal of molecular spectroscopy, 166(1), 1994, pp. 79-87
Citations number
6
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Linestrengths have been measured for three weak bands of (N2O)-N-14-O-
16 using a Fourier transform spectrometer, with an effective response
function width of about 5 X 10(-3) cm-1. The observed bands are the co
ld band nu1 + 3nu2, and the hot bands 10(0)1 <-- 01(1)0 and 30(0)0 <--
02(0)0. Measurements have been performed with a relative accuracy bet
ter than 2%. Analysis of the results yields the squared vibrational tr
ansition dipole moments and the parameters describing the vibration-ro
tation interaction effects. It may be emphasized that, for the 10(0)1
<-- 01(1)0 transition, the corresponding quadratic Herman-Wallis param
eters are found to be in good agreement with our previous predictions
carried out according to Watson's theory. (C) 1994 Academic Press, Inc
.