CONSECUTIVE CARBON-CARBON BOND FORMATION VIA THE PI-ALLYLPALLADIUM VARIANT OF THE HECK REACTION

Authors
NYLUND CS KLOPP JM WEINREB SM
Citation
Cs. Nylund et al., CONSECUTIVE CARBON-CARBON BOND FORMATION VIA THE PI-ALLYLPALLADIUM VARIANT OF THE HECK REACTION, Tetrahedron letters, 35(25), 1994, pp. 4287-4290
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
25
Year of publication
1994
Pages
4287 - 4290
Database
ISI
SICI code
0040-4039(1994)35:25<4287:CCBFVT>2.0.ZU;2-F
Abstract
Two C-C bonds are readily formed by nucleophilic addition of stabilize d carbanions to the pi-allylpalladium intermediate regioselectively pr oduced by the Heck reaction of a vinyl bromide and an unactivated olef in. An intramolecular version of this condensation gives functionalize d carbobicyclic compounds as products.