DEMONSTRATION OF THE SYNTHETIC UTILITY OF THE GENERATION OF ALKOXY RADICALS BY THE PHOTOINDUCED, HOMOLYTIC DISSOCIATION OF ALKYL 4-NITROBENZENESULFENATES

Authors
PASTO DJ COTTARD F
Citation
Dj. Pasto et F. Cottard, DEMONSTRATION OF THE SYNTHETIC UTILITY OF THE GENERATION OF ALKOXY RADICALS BY THE PHOTOINDUCED, HOMOLYTIC DISSOCIATION OF ALKYL 4-NITROBENZENESULFENATES, Tetrahedron letters, 35(25), 1994, pp. 4303-4306
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
25
Year of publication
1994
Pages
4303 - 4306
Database
ISI
SICI code
0040-4039(1994)35:25<4303:DOTSUO>2.0.ZU;2-1
Abstract
The synthetic utility of the generation and study of the reactions of alkoxy radicals generated by the photo-induced, homolytic dissociation of alkyl 4-nitrobenzenesulfenates is demonstrated. The efficient form ation of remotely substituted alcohol derivatives, and the addition of the alkoxy radical to a remotely situated C=C is illustrated.