Pump-probe beam measurements performed with semiconductor doped glasse
s (CdSxSe1-x and CdSe), which are specially prepared to avoid diffusio
n-limited aggregation processes, revealed a homogeneous width (FWHM) a
s small as 11 meV (90 cm-1). Narrow-band nonlinear response provides a
n analysis of absorption fine structures as well as of phase relaxatio
n features of excitons and biexcitons in quantum dots. A drastic influ
ence of the growth dynamics on the optical properties of crystallites
embedded in glass matrix is outlined.