Transient holes were burnt and probed with microsecond resolution in t
he 5D0 <-- --> F-7(0) transition of Eu3+ doped in a silicate glass fib
er. The holes are due to population storage in the 5D0 excited state f
or delays of microseconds, and to optical pumping of nuclear quadrupol
e levels for delays of seconds. Side- and anti-holes were observed. Th
e corresponding nuclear quadrupole splittings vary strongly with excit
ation wavelength. Spectral diffusion was found between mus and s. The
temperature and wavelength dependence of hole widths was determined.