Wm. Deazevedo et al., RARE-EARTH EXCITED-STATE QUENCHING AS A PROBE TO EXCIPLEX FORMATION IN POLYETHYLENE PHTHALATE DOPED WITH THE EU(PYA)32H2O COMPLEX, Journal of luminescence, 60-1, 1994, pp. 493-496
We present and discuss the results of lifetime measurements of the lum
inescence of polyethylene phthalate containing the Eu(pya)3.2H2O compl
ex (pya = pyrazine carboxylate). The variation of the lifetime of the
5D0 level of the Eu3+ ion with the excitation wavelength is attributed
to the formation of an exciplex involving the pya and polymer chain.