S. Iwai et al., FEMTOSECOND SPECTROSCOPY OF SELF-TRAPPING PROCESSES OF HOLES AND EXCITONS IN ALKALI-HALIDES, Journal of luminescence, 60-1, 1994, pp. 720-722
By pump and probe experiments we investigated self-trapping processes
of holes and excitons in KI and RbI crystals. It is found that a free
hole is relaxed initially into a one-center self-trapped hole (small p
olaron) and subsequently a two-center self-trapped hole (V(k) center)
is formed. The self-trapping of electron-hole pairs involves a one-cen
ter self-trapped hole correlated with an electron as a precursor state
for a self-trapped exciton.