STOICHIOMETRIC ALKYNE METATHESIS AT METAL CLUSTER COMPOUNDS - INTERCONVERSION OF OS3W ALKYNE ALKYLIDYNE AND DIMETALLOALLYL CLUSTERS

Authors
KUO MT HWANG DK LIU CS CHI Y PENG SM LEE GH
Citation
Mt. Kuo et al., STOICHIOMETRIC ALKYNE METATHESIS AT METAL CLUSTER COMPOUNDS - INTERCONVERSION OF OS3W ALKYNE ALKYLIDYNE AND DIMETALLOALLYL CLUSTERS, Organometallics, 13(6), 1994, pp. 2142-2144
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
6
Year of publication
1994
Pages
2142 - 2144
Database
ISI
SICI code
0276-7333(1994)13:6<2142:SAMAMC>2.0.ZU;2-5
Abstract
Treatment of Os3(CO)10(C2Me2) with CpW-(CO)2(=CTol) produced the alkyl idyne-alkyne cluster CpWOs3(CO)10(mu3-CMe)(CMeCTol) (2) and the dimeta lloallyl complex CpWOs3(CO)9[C(Me)C(Me)C(Tol)] (3) in sequence. Thermo lysis of 3 induced the selective scission of one C-C bond to give a se cond alkylidyne-alkyne cluster, CpWOs3(CO)8(mu3-CTol)(C2Me2) (4), prov iding a model of alkyne metathesis through a dimetalloallyl intermedia te.