FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE STUDIES OF GAS-PHASE REACTIONS BETWEEN TUNGSTEN IONS AND HYDROCARBONS

Authors
KIKHTENKO AV GONCHAROV VB MOMOT KI ZAMARAEV KI
Citation
Av. Kikhtenko et al., FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE STUDIES OF GAS-PHASE REACTIONS BETWEEN TUNGSTEN IONS AND HYDROCARBONS, Organometallics, 13(6), 1994, pp. 2536-2538
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
6
Year of publication
1994
Pages
2536 - 2538
Database
ISI
SICI code
0276-7333(1994)13:6<2536:FIRSOG>2.0.ZU;2-R
Abstract
FT/ICR spectrometry has been used for gas-phase studies of the interac tion between singly-charged positive tungsten ions and hydrocarbons (a lkanes C2-C-9, alkenes C2-C6, and cycloalkanes C3-C6). It is shown tha t this interaction results mainly in dehydrogenation products. The num ber of H-2 molecules eliminated depends upon the size and type of hydr ocarbon and varies from 1 to 6. Significant amounts of C-C cleavage pr oducts have been found in the cases of cyclopropane and 2-methylpropen e only.