Jm. Spaeth et al., CROSS-RELAXATION IN MAGNETIC-RESONANCE AS A TOOL TO STUDY SPATIAL CORRELATIONS BETWEEN DEFECTS IN INSULATORS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 91(1-4), 1994, pp. 175-182
Direct experimental evidence for the spatial correlation between param
agnetic defects can be obtained by measuring the dipole-dipole interac
tion-induced cross relaxation effects between the defects using optica
l detection of the electron paramagnetic resonance via the magnetic ci
rcular dichroism of the absorption. This novel experimental method is
explained. It is applied to the formation of F and H centres during re
laxation of the self-trapped exciton in KBr at 1.5 K. Direct experimen
tal evidence is presented that F and H centres are separated by four l
attice spacings along [110] directions. This correlation is lost after
warming to 30 K when H centres can diffuse away.