H. Fladry et al., ION-BEAM-INDUCED ADHESION IMPROVEMENT OF METAL LAYERS - A COMPARATIVE-STUDY ON COMPOSITE LAYERS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 91(1-4), 1994, pp. 575-579
The adhesion of thin layers of metals like Al, Cu, Cr, Ti etc. on poly
mer, ceramic or composite substrates is of great importance for microe
lectronics (printed circuits, packaging), and materials science. There
fore investigations on the adhesion improvement of copper on high temp
erature thermoplasts, carbon fibre reinforced polymers (CFK) and pure
carbon by ion bombardment were undertaken. Ion beam mixing as well as
ion beam assisted deposition (IBAD) was applied. It was shown that the
electronic stopping power is the most important parameter for adhesio
n in the case of ion beam mixing by non-reactive ions. Reactive ions,
especially metals, add an important chemical effect when stopped near
the interface. IBAD Cu-layers have only good adhesion properties when
prepared by low energy ion bombardment or with reactive intermediate l
ayers.