ALTERING THE STEREOCHEMISTRY OF ALLYLATION REACTIONS OF CYCLIC ALPHA-SULFINYL RADICALS WITH DIARYLUREAS

Authors
CURRAN DP KUO LH
Citation
Dp. Curran et Lh. Kuo, ALTERING THE STEREOCHEMISTRY OF ALLYLATION REACTIONS OF CYCLIC ALPHA-SULFINYL RADICALS WITH DIARYLUREAS, Journal of organic chemistry, 59(12), 1994, pp. 3259-3261
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
12
Year of publication
1994
Pages
3259 - 3261
Database
ISI
SICI code
0022-3263(1994)59:12<3259:ATSOAR>2.0.ZU;2-R
Abstract
Radical allylations of 2-(phenylseleno)tetrahydrothiophene oxide and 2 -benzyl-5-(phenylseleno)3-isothiazolidone 1-oxide with allyltributylst annane in the presence of N-bis[3-(trifluoromethyl)-5-(carbooctyloxy)p henyl] urea have been investigated. This urea was shown to be about as selective at promoting formation of trans-2-allyltetrahydrothiophene oxide and trans-5-allyl-2-benzyl-3-isothiazolidone 1-oxide as hydrogen bonding solvents and Lewis acids.