OPTICALLY PURE HALOSELENURANES - FIRST SYNTHESIS AND NUCLEOPHILIC SUBSTITUTIONS

Authors
TAKAHASHI T KUROSE N KAWANAMI S ARAI Y KOIZUMI T SHIRO M
Citation
T. Takahashi et al., OPTICALLY PURE HALOSELENURANES - FIRST SYNTHESIS AND NUCLEOPHILIC SUBSTITUTIONS, Journal of organic chemistry, 59(12), 1994, pp. 3262-3264
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
12
Year of publication
1994
Pages
3262 - 3264
Database
ISI
SICI code
0022-3263(1994)59:12<3262:OPH-FS>2.0.ZU;2-X
Abstract
The first synthesis of optically pure haloselenuranes 1 has been accom plished by utilizing the 2-exehydroxy-10-bornyl group as a chiral liga nd. Complete retention of the configuration has been observed in inter conversion reactions between haloselenuranes 1 and selenoxide 2 and in nucleophilic substitution reactions of 1.