INTERFERENCE EFFECTS AND THEIR ELIMINATION BY STANDARD ADDITION AND SUCCESSIVE DILUTION METHOD AT THE MERCURY DETERMINATION BY CONTINUOUS-FLOW COLD VAPOR ATOMIC-ABSORPTION SPECTROMETRY
L. Pszonicki et al., INTERFERENCE EFFECTS AND THEIR ELIMINATION BY STANDARD ADDITION AND SUCCESSIVE DILUTION METHOD AT THE MERCURY DETERMINATION BY CONTINUOUS-FLOW COLD VAPOR ATOMIC-ABSORPTION SPECTROMETRY, Chemia Analityczna, 39(2), 1994, pp. 205-215
The general character of the interference effects occurring in the con
tinuous flow old vapour technique was estimated. It was found that all
elements, which are reduced together with the mercury either to their
elemental form or to the form of unstable volatile hydrides that deco
mpose at the room temperature, are the virtual interferents. The mecha
nism of interferences has been proposed.It was found that the standard
addition and successive dilution (SASD) method may be used successful
ly for evaluation of analytical signals measured by this technique in
the presence of interferents. It was also found that the equipment sys
tem can memorize the interference effects and deform the results of th
e successive samples.