OFF-RESONANCE ROESY FOR THE STUDY OF DYNAMIC PROCESSES

Authors
DESVAUX H BERTHAULT P BIRLIRAKIS N GOLDMAN M
Citation
H. Desvaux et al., OFF-RESONANCE ROESY FOR THE STUDY OF DYNAMIC PROCESSES, Journal of magnetic resonance. Series A, 108(2), 1994, pp. 219-229
Citations number
64
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Journal of magnetic resonance. Series A → ACNP
ISSN journal
10641858
Volume
108
Issue
2
Year of publication
1994
Pages
219 - 229
Database
ISI
SICI code
1064-1858(1994)108:2<219:ORFTSO>2.0.ZU;2-K
Abstract
The method of off-resonance ROESY consists of studying relaxation in t he presence of a strong off-resonance irradiation. Its theory is devel oped under very general assumptions and its advantages are described o ver more standard methods: suppression of HOHAHA transfers and possibi lity by the appropriate choice of the effective field to check the onl y existence of dipolar relaxation, to investigate internuclear dynamic s, or to isolate the study of chemical exchange. Experimental illustra tions are given for some of the predictions. (C) 1994 Academic Press, Inc.