CLUSTERING PROCESS INSIDE THE SR1-XMX''F2-SOLUTIONS(2X (M''=TH, U) SOLID)

Authors
REAU JM JUN XY SENEGAS J
Citation
Jm. Reau et al., CLUSTERING PROCESS INSIDE THE SR1-XMX''F2-SOLUTIONS(2X (M''=TH, U) SOLID), Physica status solidi. a, Applied research, 143(1), 1994, pp. 51-58
Citations number
13
Categorie Soggetti
Physics, Condensed Matter
Journal title
Physica status solidi. a, Applied research → ACNP
ISSN journal
00318965
Volume
143
Issue
1
Year of publication
1994
Pages
51 - 58
Database
ISI
SICI code
0031-8965(1994)143:1<51:CPITS(>2.0.ZU;2-V
Abstract
The Sr1-xMx''F2+2x (M'' = Th. U) solid solutions appear as characteriz ed by the same clustering process as the Ca1-xMx''F2+2x ones: progress ive transformation with increasing x of 4:0:3:3 clusters into 1:0:3: 0 clusters. Comparison of the short-range structure and electrical prop erties of the M1-xMxF2+2x (M = Ca, Sr; M'' = Th, U) solid solutions sh ows that the fluoride ion conductivity in these materials is essential ly bound to the mobility of charge carriers, whereas their number depe nds on structural constraints.