PREPARATION AND PROPERTIES OF 3-ALLYL(HALO)TRIS(TRIMETHYLPHOSPHINE)RUTHENIUM(II) COMPLEXES AND THEIR DERIVATIVES

Authors
MARUYAMA Y SHIMIZU I YAMAMOTO A
Citation
Y. Maruyama et al., PREPARATION AND PROPERTIES OF 3-ALLYL(HALO)TRIS(TRIMETHYLPHOSPHINE)RUTHENIUM(II) COMPLEXES AND THEIR DERIVATIVES, Chemistry Letters, (6), 1994, pp. 1041-1044
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1994
Pages
1041 - 1044
Database
ISI
SICI code
0366-7022(1994):6<1041:PAPO3>2.0.ZU;2-4
Abstract
Oxidative addition of allyl halides to Ru(cod)(cot) (cod = 1,5-cyclooc tadiene, cot = 1,3,5-cyclooctatriene) in the presence of trimethylphos phine at 50 OC in benzene gives Ru(eta(3)-allyl)(PMe(3))(3)X (X=Br, Cl ), which reacted with PhCHO to yield homoallylic alcohols, and with CO to afford an eta(2)-acyl complex, RuBr(CO)(PMe(3))(2)(eta(2)-COCH2CH= CH2), and an (eta(1)-allyl)ruthenium(II) complex, RuBr(CO)(2)(PMe(3))( 2)(eta(1)-allyl).