TRANSITION-METAL PHOSPHINE COMPLEXES POSSESSING PHASE-TRANSFER FUNCTION - PREPARATION AND REACTIVITIES OF PALLADIUM COMPLEXES CONTAINING QUATERNARY AMMONIUM GROUPS

Authors
OKANO T HARADA N KIJI J
Citation
T. Okano et al., TRANSITION-METAL PHOSPHINE COMPLEXES POSSESSING PHASE-TRANSFER FUNCTION - PREPARATION AND REACTIVITIES OF PALLADIUM COMPLEXES CONTAINING QUATERNARY AMMONIUM GROUPS, Chemistry Letters, (6), 1994, pp. 1057-1060
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1994
Pages
1057 - 1060
Database
ISI
SICI code
0366-7022(1994):6<1057:TPCPPF>2.0.ZU;2-7
Abstract
A new type of phosphine ligands (L) bearing quaternary ammonium as a f unctional group was synthesized. Their palladium complexes, PdBr(2)L(2 ), readily underwent halogen exchange with powdered NaI under two-phas e conditions, and efficiently catalyzed the fluorocarbonylation of phe nyl bromide with powdered KF at atmospheric pressure of CO.