A NEW APPROACH TO THE SYNTHESIS OF GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED MACROLIDES AND (-)-PYRENOPHORIN BY INTRAMOLECULAR C=C BOND FORMATION WITH OXIDATIVE FUNCTIONALIZATION FROM EGA-[ALPHA-(P-CHLOROPHENYLSULFINYL)ACETOXY]ALKANAL

Authors
NOKAMI J TANIGUCHI T GOMYO S KAKIHARA T
Citation
J. Nokami et al., A NEW APPROACH TO THE SYNTHESIS OF GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED MACROLIDES AND (-)-PYRENOPHORIN BY INTRAMOLECULAR C=C BOND FORMATION WITH OXIDATIVE FUNCTIONALIZATION FROM EGA-[ALPHA-(P-CHLOROPHENYLSULFINYL)ACETOXY]ALKANAL, Chemistry Letters, (6), 1994, pp. 1103-1106
Citations number
41
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1994
Pages
1103 - 1106
Database
ISI
SICI code
0366-7022(1994):6<1103:ANATTS>2.0.ZU;2-Y
Abstract
The title compounds were prepared via the intramolecular condensation reaction of lpha-(p-chlorophenylsulfinyl)acetoxy]tridecanal(or dodecan al) or via the combination of inter- and intramolecular condensation o f 5-[alpha-(p-chlorophenylsulfinyl)acetoxy]hexanal in the presence of piperidine.