SYNTHESIS OF DIALLYLAMINES AND TRIALLYLAM INES FROM 3-ACETOXY-3-ARYL-2-METHYLENE PROPIONITRILES AND METHYL 3-ACETOXY-3-ARYL-2-METHYLENE PROPIONATES

Authors
AKSSIRA M ELGUEMMOUT F BAUCHAT P FOUCAUD A
Citation
M. Akssira et al., SYNTHESIS OF DIALLYLAMINES AND TRIALLYLAM INES FROM 3-ACETOXY-3-ARYL-2-METHYLENE PROPIONITRILES AND METHYL 3-ACETOXY-3-ARYL-2-METHYLENE PROPIONATES, Canadian journal of chemistry, 72(5), 1994, pp. 1357-1361
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
72
Issue
5
Year of publication
1994
Pages
1357 - 1361
Database
ISI
SICI code
0008-4042(1994)72:5<1357:SODATI>2.0.ZU;2-C
Abstract
The reactions of 3-acetoxy-3-aryl-2-methylene propionitriles 1 with am monia yielded the corresponding diallylamines 3ZZ. The reaction of 1 w ith a primary allylamine or with ethylene diamine gave the diallylamin e 11 or 13ZZ. The treatment of methyl 3-acetoxy-3-aryl-2-methylene pro pionates 2 with isopropylamine or ethylene diamine gave the allylamine s 6EE or 14 and 15, but the reaction of 2 with ammonia gave only the t riallylamines 4EEE in good yields.