SOLUBILITY AND SOLVATION OF PYRONATO AND PYRIDINATO COMPLEXES OF ALUMINUM, GALLIUM, AND INDIUM IN ALCOHOL-WATER MIXTURES

Authors
BEATTY E BURGESS J PATEL MS
Citation
E. Beatty et al., SOLUBILITY AND SOLVATION OF PYRONATO AND PYRIDINATO COMPLEXES OF ALUMINUM, GALLIUM, AND INDIUM IN ALCOHOL-WATER MIXTURES, Canadian journal of chemistry, 72(5), 1994, pp. 1370-1375
Citations number
41
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
72
Issue
5
Year of publication
1994
Pages
1370 - 1375
Database
ISI
SICI code
0008-4042(1994)72:5<1370:SASOPA>2.0.ZU;2-Q
Abstract
Solubilities are reported for aluminum, gallium, and indium tris-ligan d complexes of the pyrones maltol and ethylmaltol and of a number of 4 -pyridinones in water-methanol and water-tert-butyl alcohol solvent mi xtures, at 298.2 K. Trends and patterns in transfer chemical potential s derived from these solubilities are discussed in terms of the depend ence of solvation on the nature of the ligand, the metal, and the coso lvent.