VACUUM-ULTRAVIOLET FOURIER-TRANSFORM SPECTROSCOPY OF THE DELTA(0,0) AND BETA(7,0) BANDS OF NO

Citation
Je. Murray et al., VACUUM-ULTRAVIOLET FOURIER-TRANSFORM SPECTROSCOPY OF THE DELTA(0,0) AND BETA(7,0) BANDS OF NO, The Journal of chemical physics, 101(1), 1994, pp. 62-73
Citations number
35
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
101
Issue
1
Year of publication
1994
Pages
62 - 73
Database
ISI
SICI code
0021-9606(1994)101:1<62:VFSOTD>2.0.ZU;2-S
Abstract
The combined band oscillator strength of the delta(0,0) and beta(7,0) bands of nitric oxide has been measured in absorption by utilizing a v acuum ultraviolet Fourier transform spectrometer to resolve the rotati onal line profiles. We give accurate rotational line positions of the delta(0,0) and beta(7,0) bands, and improved term values up to J=19.5 for the C (2) Pi(upsilon = 0) and J=8.5 for the B (2) Pi(upsilon = 7) levels, measured from the ground state. A deperturbation procedure has been used on the mixed levels, and the calculated molecular constants are in good agreement with previous work.