SINGULARITIES IN THE CONSISTENT HYPERNETTED-CHAIN APPROXIMATION

Citation
Pg. Ferreira et al., SINGULARITIES IN THE CONSISTENT HYPERNETTED-CHAIN APPROXIMATION, The Journal of chemical physics, 101(1), 1994, pp. 594-602
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
101
Issue
1
Year of publication
1994
Pages
594 - 602
Database
ISI
SICI code
0021-9606(1994)101:1<594:SITCHA>2.0.ZU;2-Z
Abstract
We use the consistent set of hypernetted chain (HNC) equations to inve stigate the stability of liquid and vapor phases of simple fluids. We calculate the phase diagram and discuss the physical (spinodal) and ma thematical (termination line) singularities of the theory. The latter delimits a region where the HNC equations have no physically acceptabl e solutions. Additionally, we confirm that the physical solutions of t he HNC equation correspond to local minima of the consistent grand pot ential which, however, appears to be unbounded from below.