N. Chanana et al., PATH INTEGRATION OF A GENERAL 2 TIME ACTION INVOLVING LOCAL AND NONLOCAL HARMONIC-OSCILLATOR POTENTIALS, The Journal of chemical physics, 101(1), 1994, pp. 651-661
Path integration of a general two-time quadratic action having local a
nd nonlocal harmonic oscillator potentials is performed within the fra
mework of Feynman's polygonal path approach. The propagator (or the de
nsity matrix) thus obtained is diagonalized and the values of energies
and eigenfunctions of a large number of states as a function of the s
trength of the nonlocal potential which simulates the effect of the me
dium on the solute represented by the local harmonic oscillator potent
ial are derived. These values are used to calculate the effect of the
solvent on the various properties of the solute. The possibility of re
presenting the propagator in terms of an effective local action is als
o explored.