Magnetotransport measurements have been carried out under hydrostatic
pressure on [001]- and [111]-oriented InAs/GaSb structures grown by me
tal-organic vapor-phase epitaxy. The system is semimetallic at zero pr
essure, but as the pressure is increased, electrons, located in the In
As layers, transfer back into the valence band of GaSb and a semimetal
-to-semiconductor transition is observed. In double heterojunctions th
e zero band overlap condition occurs at 14 and 17 kbar for the [001] a
nd [111]A orientations, respectively. The band crossing at the interfa
ce has been calculated self-consistently for the two orientations, tak
ing into account the intrinsic and extrinsic origins of the carriers.
This band overlap is found not only to be strongly orientation depende
nt, approximately 60 meV larger in [111]A compared with [001], but als
o to decrease at rates of 10 and 12 meV/kbar for the [001] and [111]A
orientations, respectively. These rates are much larger than those det
ermined from molecular beam epitaxy samples, but closer to the variati
on with pressure of the band gaps of the bulk materials.