A ''molecular tribometer'' has been constructed [1] that measures dire
ctly, with great accuracy, the forces and the displacements that act b
etween metallic surfaces bearing organic layers in a liquid medium as
they slide past each other. Its originality is due to its low complian
ces (2 x 10(-7) m N-1 for the normal direction, 2 x 10(-6) m N-1 for t
he two other directions), which permit mechanical control of the thin
layer. In this work, it is shown that an anisotropic thin monolayer of
stearic acid adsorbed an each cobalt surface is more compliant than t
he contact of the cobalt surfaces and hence reduces the apparent shear
moduli of the contact zone and controls the shear process. The ''inte
rfacial'' friction depends on the sliding speed and is very sensitive
to the very small variations of the film interface thickness. Two comp
etitive and opposing processes occur during the sliding: crushing and
lifting of the monolayer. It is suggested that the crushing appears at
very low speed, when the transit time is close to that of the molecul
es monolayer. Our findings have direct applications for the properties
of boundary lubricants and for the rheological behaviour of both surf
actant and polymer molecules.