SYNTHESIS, STRUCTURE AND RESOLUTION OF A DINUCLEAR CO-III TRIPLE-HELIX

Authors
CHARBONNIERE LJ BERNARDINELLI G PIGUET C SARGESON AM WILLIAMS AF
Citation
Lj. Charbonniere et al., SYNTHESIS, STRUCTURE AND RESOLUTION OF A DINUCLEAR CO-III TRIPLE-HELIX, Journal of the Chemical Society, Chemical Communications, (12), 1994, pp. 1419-1420
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1994
Pages
1419 - 1420
Database
ISI
SICI code
0022-4936(1994):12<1419:SSAROA>2.0.ZU;2-K
Abstract
For the first time a helical dinuclear metal complex has been separate d into enantiomers by transformation of a labile cobalt(ii) triple-hel ical complex into the kinetically stable cobalt(iir) complex [CO2(2a)( 3)](6+) which has been characterized structurally and resolved by chro matography.