PREPARATION AND CHARACTERIZATION OF A PALLADIUM-COPPER HETEROMETALLICCOMPLEX AND ITS CATALYTIC ACTIVITY TOWARDS OXIDATION OF ALKENES

Authors
HOSOKAWA T TAKANO M MURAHASHI S OZAKI H KITAGAWA Y SAKAGUCHI K KATSUBE Y
Citation
T. Hosokawa et al., PREPARATION AND CHARACTERIZATION OF A PALLADIUM-COPPER HETEROMETALLICCOMPLEX AND ITS CATALYTIC ACTIVITY TOWARDS OXIDATION OF ALKENES, Journal of the Chemical Society, Chemical Communications, (12), 1994, pp. 1433-1434
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1994
Pages
1433 - 1434
Database
ISI
SICI code
0022-4936(1994):12<1433:PACOAP>2.0.ZU;2-G
Abstract
Treatment of PdCl2(MeCN)(2) and CuCl2 with pyrrolidin-2-one L gives a novel Pd-Cu heterometallic complex having a polymeric structure of [Cl Cu(L)(4)(mu-Cl)PdCl2.PdCl2](n) which catalyses the oxidation of cycloh exene in ClCH2CH2Cl-MeOH.