EFFICIENT AND SELECTIVE CATALYTIC DEHYDROGENATION OF ALKANES USING RHODIUM(I) ARSINE COMPLEXES

Authors
MILLER JA KNOX LK
Citation
Ja. Miller et Lk. Knox, EFFICIENT AND SELECTIVE CATALYTIC DEHYDROGENATION OF ALKANES USING RHODIUM(I) ARSINE COMPLEXES, Journal of the Chemical Society, Chemical Communications, (12), 1994, pp. 1449-1450
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1994
Pages
1449 - 1450
Database
ISI
SICI code
0022-4936(1994):12<1449:EASCDO>2.0.ZU;2-1
Abstract
Arsine complexes of rhodium(I) efficiently catalyze the transfer dehyd rogenation of alkanes under an atmosphere of hydrogen, while at the sa me time producing decreased levels of 'direct hydrogenated' sacrificia l olefin relative to that derived from similar phosphine-based catalys ts.