PALLADIUM-CATALYZED CARBONYL ALLYLATION BY ISOPRENE VIA REGIOSELECTIVE 1,4-ADDITION OF TIN HYDRIDE FORMED IN-SITU

Authors
MASUYAMA Y TSUNODA M KURUSU Y
Citation
Y. Masuyama et al., PALLADIUM-CATALYZED CARBONYL ALLYLATION BY ISOPRENE VIA REGIOSELECTIVE 1,4-ADDITION OF TIN HYDRIDE FORMED IN-SITU, Journal of the Chemical Society, Chemical Communications, (12), 1994, pp. 1451-1452
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1994
Pages
1451 - 1452
Database
ISI
SICI code
0022-4936(1994):12<1451:PCABIV>2.0.ZU;2-L
Abstract
Isoprene reacts with aldehydes in the presence of a catalytic amount o f Pd(OAc)(2)-4PPh(3) or Pd(PPh(3))(4) and a stoichiometric amount of S nCl2 at 40-50 degrees C in AcOH-H2O to produce 1-substituted 2,2-dimet hyl-3-buten-1-ols regioselectively.