A NEW TEMPLATE ENCAPSULATION STRATEGY FOR LARGER CAVITY METAL-ION CAGES

Authors
GEUE RJ HOHN A RALPH SF SARGESON AM WILLIS AC
Citation
Rj. Geue et al., A NEW TEMPLATE ENCAPSULATION STRATEGY FOR LARGER CAVITY METAL-ION CAGES, Journal of the Chemical Society, Chemical Communications, (12), 1994, pp. 1513-1515
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1994
Pages
1513 - 1515
Database
ISI
SICI code
0022-4936(1994):12<1513:ANTESF>2.0.ZU;2-M
Abstract
Stereospecific sequential condensation of paraformaldehyde and propion aldehyde with a tripodal bis(triamine)cobalt(III) template rapidly enc apsulates the metal, and a subsequent facile reduction of imine functi ons gives an expanded cavity hexaazabicyclic cage system with unusual structural and chromophore electron properties, complemented by an exc eptional stability and relatively fast Co-II/III electron exchange rat es.