SMECTIC-A LIQUID SINGLE-CRYSTAL ELASTOMERS SHOWING MACROSCOPIC INPLANE FLUIDITY

Citation
E. Nishikawa et al., SMECTIC-A LIQUID SINGLE-CRYSTAL ELASTOMERS SHOWING MACROSCOPIC INPLANE FLUIDITY, Macromolecular rapid communications, 18(2), 1997, pp. 65-71
Citations number
23
Categorie Soggetti
Polymer Sciences
ISSN journal
10221336
Volume
18
Issue
2
Year of publication
1997
Pages
65 - 71
Database
ISI
SICI code
1022-1336(1997)18:2<65:SLSESM>2.0.ZU;2-#
Abstract
The mechanical response of a smectic A liquid single crystal elastomer (LSCE) to stress applied perpendicular and parallel to the layers is described. We find that the static modulus perpendicular to the layers is two orders of magnitude larger than the modulus parallel to the la yer direction, where the latter is completely due to the crosslinking. Macroscopically the width of the smectic A LSCE does not shrink when a mechanical stress is applied parallel to the layers while the length of the film increases by a factor of 2 thus demonstrating the in-plan e fluidity of the smectic layering.