NMR-STUDY OF DOPED POLY(2,5-DIMETHYLANILINE)

Authors
GENG YH JING XB LI J WANG FS
Citation
Yh. Geng et al., NMR-STUDY OF DOPED POLY(2,5-DIMETHYLANILINE), Macromolecular rapid communications, 18(2), 1997, pp. 73-81
Citations number
8
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
18
Issue
2
Year of publication
1997
Pages
73 - 81
Database
ISI
SICI code
1022-1336(1997)18:2<73:NODP>2.0.ZU;2-X
Abstract
Structure changes and charge transfer in the doping process of poly(2, 5-dimethylaniline) (PDMA) were studied by NMR technique. It was shown that not only the polymer chain but also the hydrogen atoms and methyl groups on the aromatic rings were involved in the charge transfer pro cess. A ''four ring BQ derivatives'' model was proposed to explain the NMR results.