SYNTHESIS OF AMPHIPHILIC GRAFT-COPOLYMERS BY RING-OPENING POLYMERIZATION OF 2-METHYL-2-OXAZOLINE INITIATED BY POLY[ISOBUTENE-CO-(P,M-CHLOROMETHYLSTYRENE)] MACROINITIATORS
O. Nuyken et al., SYNTHESIS OF AMPHIPHILIC GRAFT-COPOLYMERS BY RING-OPENING POLYMERIZATION OF 2-METHYL-2-OXAZOLINE INITIATED BY POLY[ISOBUTENE-CO-(P,M-CHLOROMETHYLSTYRENE)] MACROINITIATORS, Macromolecular rapid communications, 18(2), 1997, pp. 125-131
romethylstyrene)]-graft-poly(2-methyl-2-oxazoline) graft copolymers (G
P) were prepared by the ''grafting from'' method through the cationic
polymerization of 2-methyl-2-oxazoline (MeOXA) initiated by a statisti
cal copolymer is isobutene and chloromethylstyrene. The unusual viscos
ity behavior in chloroform solution of these polymers, the dynamic las
er light scattering analysis in aqueous solution, as well as the solub
ility in polar solvents Like water and methanol demonstrate the amphip
hilic character of the graft copolymers and indicate the formation of
aggregates in solution.