SYNTHESIS OF AMPHIPHILIC GRAFT-COPOLYMERS BY RING-OPENING POLYMERIZATION OF 2-METHYL-2-OXAZOLINE INITIATED BY POLY[ISOBUTENE-CO-(P,M-CHLOROMETHYLSTYRENE)] MACROINITIATORS

Citation
O. Nuyken et al., SYNTHESIS OF AMPHIPHILIC GRAFT-COPOLYMERS BY RING-OPENING POLYMERIZATION OF 2-METHYL-2-OXAZOLINE INITIATED BY POLY[ISOBUTENE-CO-(P,M-CHLOROMETHYLSTYRENE)] MACROINITIATORS, Macromolecular rapid communications, 18(2), 1997, pp. 125-131
Citations number
9
Categorie Soggetti
Polymer Sciences
ISSN journal
10221336
Volume
18
Issue
2
Year of publication
1997
Pages
125 - 131
Database
ISI
SICI code
1022-1336(1997)18:2<125:SOAGBR>2.0.ZU;2-Z
Abstract
romethylstyrene)]-graft-poly(2-methyl-2-oxazoline) graft copolymers (G P) were prepared by the ''grafting from'' method through the cationic polymerization of 2-methyl-2-oxazoline (MeOXA) initiated by a statisti cal copolymer is isobutene and chloromethylstyrene. The unusual viscos ity behavior in chloroform solution of these polymers, the dynamic las er light scattering analysis in aqueous solution, as well as the solub ility in polar solvents Like water and methanol demonstrate the amphip hilic character of the graft copolymers and indicate the formation of aggregates in solution.