MOLECULAR-INTERACTIONS IN MIXTURES OF QUINOLINE WITH SOME AROMATIC-HYDROCARBONS - ULTRASONIC, DIELECTRIC AND VISCOMETRIC STUDIES

Ultrasonic speed, isentropic compressibility, dielectric constant, ref ractive index and viscosity data of binary mixtures of quinoline with benzene, toluene, o-xylene or p-xylene have been experimentally obtain ed over the whole composition range at 303.15 K and the interactions e xisting between the components have been discussed. These studies sugg est the existence of strong specific interaction between quinoline and aromatic hydrocarbons and more than one competing factors are respons ible for the observed excess values of these properties. Molar polariz abilities, apparent polarizabilities, equilibrium constants, apparent dipole moments and Kirkwood correlation parameters for these mixtures have also been evaluated and the results indicate complexation between the molecules of quinoline and aromatic hydrocarbons. Various interac tion parameters and excess Gibbs energy of flow have been evaluated fr om the viscosity data.