A NOVEL SYNTHESIS OF 2 N-SUBSTITUTED PIPERIDONES

Citation
Tm. Ikramuddeen et al., A NOVEL SYNTHESIS OF 2 N-SUBSTITUTED PIPERIDONES, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 33(4), 1994, pp. 362-364
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03764699
Volume
33
Issue
4
Year of publication
1994
Pages
362 - 364
Database
ISI
SICI code
0376-4699(1994)33:4<362:ANSO2N>2.0.ZU;2-9
Abstract
The reaction of piperidones (1) with ethyl alpha-(bromomethyl)acrylate under Reformatsky conditions furnishes, instead of the anticipated sp iro alpha-methylene-gamma-butyrolactones (2), the N-substituted piperi dones (3). Their structures have been determined by mass, H-1 NMR and C-13 NMR spectral data.