CONFORMATIONAL DYNAMICS AND THE ROTATIONAL ISOMERIC STATE APPROXIMATION FOR ALKYL CHAINS

Citation
R. Cassol et al., CONFORMATIONAL DYNAMICS AND THE ROTATIONAL ISOMERIC STATE APPROXIMATION FOR ALKYL CHAINS, Journal of physics. Condensed matter, 6, 1994, pp. 10000279-10000284
Citations number
16
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09538984
Volume
6
Year of publication
1994
Supplement
23
Pages
10000279 - 10000284
Database
ISI
SICI code
0953-8984(1994)6:<10000279:CDATRI>2.0.ZU;2-3
Abstract
The assumption of a timescale separation between conformational kineti cs and torsional modes, implicit in the rotational isomeric state appr oximation, is analysed on the basis of asymptotic solutions of a multi dimensional diffusion equation.