THE ISOLATION, CHARACTERIZATION AND OXIDA TION REACTION OF ACTIVE INTERMEDIATES OF CYTOCHROME-P-450 MODEL SYSTEM OXOCHROMIUM(V) TETRAPHENYLPORPHYRIN COMPLEXES

Authors
SHU HM GU SZ JIN RZ LIU YS JIN ZS
Citation
Hm. Shu et al., THE ISOLATION, CHARACTERIZATION AND OXIDA TION REACTION OF ACTIVE INTERMEDIATES OF CYTOCHROME-P-450 MODEL SYSTEM OXOCHROMIUM(V) TETRAPHENYLPORPHYRIN COMPLEXES, Huaxue xuebao, 52(5), 1994, pp. 468-473
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
52
Issue
5
Year of publication
1994
Pages
468 - 473
Database
ISI
SICI code
0567-7351(1994)52:5<468:TICAOT>2.0.ZU;2-G
Abstract
Oxochromium (V) tetraphenylporphyrin complexes, O = Cr (V) TPP (Cl) Ph I. O = Cr-(V) TPP (N3) PhI and O = Cr (V)TPP (p-CH3OC6H4O)1/2PhI were isolated from the reaction of Cr (III) TPP (Cl). Cr (III) TPP (N3) Py or Cr (III) TPP (p-CH3OC6H4O) THF with iodosylbenzene in dichlorometha ne at -40-degrees-C under nitrogen. They were characterized by element al analyses. visible. infrared. ESR, NMR and mass spectra. They can ox idize styrene. cyclohexanol, cyclohexene and cyclohexane. They are the active intermediates of cytochrome P-450 model systems.