TRIMETHYL PHOSPHATE INDUCED DECOMPOSITION OF KAOLINITE

The decomposition of kaolinite by treatment with trimethyl phosphate ( TMP) and the composition of the new crystalline phase formed were stud ied. On hot treatment with TMP, kaolinite forms a crystalline white co mpound that is soluble in hot water. The X-ray diffraction pattern of the kaolinite treated shows both the typical reflections of kaolinite and, furthermore, a very strong reflection at 8.84 angstrom. After 30 days of treatment with TMP, the silicate structure of kaolinite is com pletely destroyed and a crystalline phase identical with that resultin g from treatment of aluminium oxide (Al2O3) with TMP is formed. The re sults show that the compound in question is formed by hydrolysis of TM P, catalyzed by the hydration water of exchange cations of kaolinite, followed by removal of Al from the silicate structure by incompletely hydrolyzed TMP. The new crystalline phase thus formed is an aluminium alkyl phosphate of formula Al(CH3)6(PO4)3.