APPLICATION OF THE MODEL OF ASSOCIATED SOLUTION TO LIQUID-METAL SYSTEMS WITH NEGATIVE DEVIATION FROM RAOULT LAW

Citation
Ag. Morachevskii et al., APPLICATION OF THE MODEL OF ASSOCIATED SOLUTION TO LIQUID-METAL SYSTEMS WITH NEGATIVE DEVIATION FROM RAOULT LAW, Russian journal of applied chemistry, 66(7), 1993, pp. 147-1151
Citations number
42
Categorie Soggetti
Chemistry Applied
ISSN journal
10704272
Volume
66
Issue
7
Year of publication
1993
Part
1
Pages
147 - 1151
Database
ISI
SICI code
1070-4272(1993)66:7<147:AOTMOA>2.0.ZU;2-P
Abstract
The concentration dependence of thermodynamic functions of binary liqu id metal systems with negative deviation from Raoult's law was describ ed using the model of ideal associated solution (IAS). Varying the num ber of associates from one to five the calculation was performed for 3 8 systems examined. The LAS model was shown to be applicable for analy tical representation of experimental data on liquid metal systems with various degree of negative deviation from ideality.