REACTIONS OF DIAZIDO DERIVATIVES OF S-TRIAZINE WITH C-NUCLEOPHILES

Authors
AZEV YA LOGINOVA IP GUSELNIKOVA OL SHORSHNEV SV RUSINOV VL CHUPAKHIN ON
Citation
Ya. Azev et al., REACTIONS OF DIAZIDO DERIVATIVES OF S-TRIAZINE WITH C-NUCLEOPHILES, Mendeleev communications, (3), 1994, pp. 104-107
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
3
Year of publication
1994
Pages
104 - 107
Database
ISI
SICI code
0959-9436(1994):3<104:RODDOS>2.0.ZU;2-E
Abstract
The reaction of 2,4-diazido-s-triazines 1 with an equimolar amount or a two-fold molar excess of ethyl cyanoacetate in the presence of triet hylamine in DMF affords the corresponding mono-2 or diamino derivative s of s-triazine 3; on heating 2,4-diazido-s-triazines 1a-d with a two- fold molar excess of acetoacetone or ethyl acetoacetate in the presenc e of triethylamine in ethanol the corresponding 1,2,3-triazolo-s-triaz ines 4a-f are formed.