The structure of MoS2/Al2O3 catalyst and the initial step of the hydro
desulfurization (HDS) reaction using an experimental model have been s
tudied by in situ Raman-, infrared emission (IRE)-, inelastic electron
tunneling (IET)-spectroscopy and thermal desorption measurements acco
mpanied by molecular modeling and EH-MO calculations. The results show
that the catalyst consists of MoS2-like crystallites which are linked
via Mo-O-Al bonds [d(Mo-O) ca. 185 pm, angle Mo-O-Al ca. 140-degrees]
almost perpendicular (but slightly inclined) to the surface of gamma-
Al2O3. A pretreatment of the surface of the MoS2 crystallites with hyd
rogen is mandatory to remove all kinds of S2 groups and to form active
(formally) Mo(II) centers at the edge positions. Thiophene, acting as
a Lewis acid only towards such centers, is destabilized upon coordina
tion and becomes susceptible for further reaction with hydrogen which
may follow, in principle, within the first steps of the route of a Bir
ch reduction. (C) 1994 Academic Press, Inc.