Mr. Denison et al., SOLID ROCKET EXHAUST IN THE STRATOSPHERE - PLUME DIFFUSION AND CHEMICAL-REACTIONS, Journal of spacecraft and rockets, 31(3), 1994, pp. 435-442
A model has been developed to examine, on a local scale, the reactions
of rocket exhaust from solid rocket motors with stratospheric ozone.
The effects were examined at two different altitudes. Results of the m
odeling study indicate that afterburning chemistry of reactive exhaust
products can cause local but transient (on the order of several minut
es) loss of ozone. The modeling study included potential heterogeneous
reactions at aluminum oxide surfaces. Results indicate that these pot
ential heterogeneous reactions do not have a major impact on the local
plume chemistry. Homogeneous reactions appear to be of more consequen
ce during the early dispersion of the plume. It has also been found th
at the rate of plume dispersion has a very significant effect on local
ozone loss.